The iron-nickel-phosphorus system: Effects on the distribution of trace elements during the evolution of iron meteorites     

Catherine M. Corrigan  Nancy L. Chabot  William F. McDonough  Sarah A. Saslow 《Geochimica et cosmochimica acta》2009,73(9):2674-6583

To better understand the partitioning behavior of elements during the formation and evolution of iron meteorites, two sets of experiments were conducted at 1 atm in the Fe-Ni-P system. The first set examined the effect of P on solid metal/liquid metal partitioning behavior of 22 elements, while the other set explored the effect of the crystal structures of body-centered cubic (α)- and face-centered cubic (γ)-solid Fe alloys on partitioning behavior. Overall, the effect of P on the partition coefficients for the majority of the elements was minimal. As, Au, Ga, Ge, Ir, Os, Pt, Re, and Sb showed slightly increasing partition coefficients with increasing P-content of the metallic liquid. Co, Cu, Pd, and Sn showed constant partition coefficients. Rh, Ru, W, and Mo showed phosphorophile (P-loving) tendencies. Parameterization models were applied to solid metal/liquid metal results for 12 elements. As, Au, Pt, and Re failed to match previous parameterization models, requiring the determination of separate parameters for the Fe-Ni-S and Fe-Ni-P systems.Experiments with coexisting α and γ Fe alloy solids produced partitioning ratios close to unity, indicating that an α versus γ Fe alloy crystal structure has only a minor influence on the partitioning behaviors of the trace element studied. A simple relationship between an element’s natural crystal structure and its α/γ partitioning ratio was not observed. If an iron meteorite crystallizes from a single metallic liquid that contains both S and P, the effect of P on the distribution of elements between the crystallizing solids and the residual liquid will be minor in comparison to the effect of S. This indicates that to a first order, fractional crystallization models of the Fe-Ni-S-P system that do not take into account P are appropriate for interpreting the evolution of iron meteorites if the effects of S are appropriately included in the effort.  相似文献   

Multiproxy approach for determination of nature and origin of carbonate micro-particles so-called “micarb” in pelagic sediments     

Catherine Beltran  Marc de Rafélis  Alain Person  Fabien Stalport  Maurice Renard 《Sedimentary Geology》2009,213(1-2):64-76

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Spatial and temporal dynamics of nitrogen exchange in an upwelling reach of a groundwater-fed river and potential response to perturbations changing rainfall patterns under UK climate change scenarios     

Ann Louise Heathwaite  Catherine Heppell  Andrew Binley  Patrick Byrne  Katrina Lansdown  Mark Trimmer  Sami Ullah  Hao Zhang 《水文研究》2021,35(4):e14135

We report the complex spatial and temporal dynamics of hyporheic exchange flows (HEFs) and nitrogen exchange in an upwelling reach of a 200 m groundwater-fed river. We show how research combining hydrological measurement, geophysics and isotopes, together with nutrient speciation techniques provides insight on nitrogen pathways and transformations that could not have been captured otherwise, including a zone of vertical preferential discharge of nitrate from deeper groundwater, and a zone of rapid denitrification linking the floodplain with the riverbed. Nitrate attenuation in the reach is dominated by denitrification but is spatially highly variable. This variability is driven by groundwater flow pathways and landscape setting, which influences hyporheic flow, residence time and nitrate removal. We observed the spatial connectivity of the river to the riparian zone is important because zones of horizontal preferential discharge supply organic matter from the floodplain and create anoxic riverbed conditions with overlapping zones of nitrification potential and denitrification activity that peaked 10–20 cm below the riverbed. Our data also show that temporal variability in water pathways in the reach is driven by changes in stage of the order of tens of centimetres and by strength of water flux, which may influence the depth of delivery of dissolved organic carbon. The temporal variability is sensitive to changes to river flows under UK climate projections that anticipate a 14%–15% increase in regional median winter rainfall and a 14%–19% reduction in summer rainfall. Superimposed on seasonal projections is more intensive storm activity that will likely lead to a more dynamic and inherently complex (hydrologically and biogeochemically) hyporheic zone. We recorded direct evidence of suppression of upwelling groundwater (flow reversal) during rainfall events. Such flow reversal may fuel riverbed sediments whereby delivery of organic carbon to depth, and higher denitrification rates in HEFs might act in concert to make nitrate removal in the riverbed more efficient.  相似文献   

The dark matter environment of the Abell 901/902 supercluster: a weak lensing analysis of the HST STAGES survey     

Catherine Heymans  Meghan E. Gray  Chien Y. Peng  Ludovic Van Waerbeke  Eric F. Bell  Christian Wolf  David Bacon  Michael Balogh  Fabio D. Barazza  Marco Barden  Asmus Böhm  John A. R. Caldwell  Boris Häußler  Knud Jahnke  Shardha Jogee  Eelco van Kampen  Kyle Lane  Daniel H. McIntosh  Klaus Meisenheimer  Yannick Mellier  Sebastian F. Sánchez  y N. Taylor  Lutz Wisotzki  Xianzhong Zheng 《Monthly notices of the Royal Astronomical Society》2008,385(3):1431-1442

We present a high-resolution dark matter reconstruction of the   z = 0.165  Abell 901/902 supercluster from a weak lensing analysis of the Hubble Space Telescope STAGES survey. We detect the four main structures of the supercluster at high significance, resolving substructure within and between the clusters. We find that the distribution of dark matter is well traced by the cluster galaxies, with the brightest cluster galaxies marking out the strongest peaks in the dark matter distribution. We also find a significant extension of the dark matter distribution of Abell 901a in the direction of an infalling X-ray group Abell 901α. We present mass, mass-to-light and mass-to-stellar mass ratio measurements of the structures and substructures that we detect. We find no evidence for variation of the mass-to-light and mass-to-stellar mass ratio between the different clusters. We compare our space-based lensing analysis with an earlier ground-based lensing analysis of the supercluster to demonstrate the importance of space-based imaging for future weak lensing dark matter 'observations'.  相似文献   

Radar topography of domes on planetary surfaces     

Catherine D. Neish  Ralph D. Lorenz 《Icarus》2008,196(2):552-564

We investigate the possibility of measuring the heights and morphology of viscously emplaced domes using radar imagery. We accurately reproduce the known height and shape of a terrestrial salt dome, and estimate the heights of several venusian pancake domes to within a factor of two. The terrestrial salt dome is consistent with a Bingham flow, while the much larger venusian pancake domes are consistent with a Newtonian flow. Applying the same techniques to Ganesa Macula, a potential cryovolcanic dome on Titan, we estimate a height between 2.0-4.9 km. Additional factors such as variable roughness and composition might account for some of the discrepancies observed.  相似文献   

The recognition of former melt flux through high‐strain zones          下载免费PDF全文

Catherine A. Stuart  Sandra Piazolo  Nathan R. Daczko 《Journal of Metamorphic Geology》2018,36(8):1049-1069

High‐strain zones are potential pathways of melt migration through the crust. However, the identification of melt‐present high‐strain deformation is commonly limited to cases where the interpreted volume of melt “frozen” within the high‐strain zone is high (>10%). In this contribution, we examine high‐strain zones in the Pembroke Granulite, an otherwise low‐strain outcrop of volcanic arc lower crust exposed in Fiordland, New Zealand. These high‐strain zones display compositional layering, flaser‐shaped mineral grains, and closely spaced foliation planes indicative of high‐strain deformation. Asymmetric leucosome surrounding peritectic garnet grains suggest deformation was synchronous with minor amounts of in situ partial melting. High‐strain zones lack typical mylonite microstructures and instead display typical equilibrium microstructures, such as straight grain boundaries, 120° triple junctions, and subhedral grain shapes. We identify five key microstructures indicative of the former presence of melt within the high‐strain zones: (a) small dihedral angles of interstitial phases; (b) elongate interstitial grains; (c) small aggregates of quartz grains with xenomorphic plagioclase grains connected in three dimensions; (d) fine‐grained, K‐feldspar bearing, multiphase aggregates with or without augite rims; and (e) mm‐ to cm‐scale felsic dykelets. Preservation of key microstructures indicates that deformation ceased as conditions crossed the solidus, breaking the positive feedback loop between deformation and the presence of melt. We propose that microstructures indicative of the former presence of melt, such as the five identified above, may be used as a tool for recognising rocks formed during melt‐present high‐strain deformation where low (<5%) volumes of leucosome are “frozen” within the high‐strain zone.  相似文献   

Titanite dates crystallization: Slow Pb diffusion during super‐solidus re‐equilibration     

Michael I. H. Hartnady  Christopher L. Kirkland  Chris Clark  Catherine V. Spaggiari  R. Hugh Smithies  Noreen J. Evans  Brad J. McDonald 《Journal of Metamorphic Geology》2019,37(6):823-838

Titanite can be found in rocks of wide compositional range, is reactive, growing or regrowing during metamorphic and hydrothermal events, and is generally amenable to U–Pb geochronology. Experimental evidence suggest that titanite has a closure temperature for Pb ranging from 550 to 650°C, and thus titanite dates are commonly interpreted as cooling ages. However, this view has been challenged in recent years by evidence from natural titanite which suggests the closure temperature may be significantly higher (up to 800°C). Here, we investigate titanite in an enclave of migmatitic gneiss included within a granite intrusion. The titanite crystals exhibit textural features characteristic of fluid‐mediated mass transfer processes on length scales of <100 µm. These textural features are associated with variation in both Pb concentrations and distinct U–Pb isotopic compositions. Zr‐in‐titanite thermometry indicates that modification of the titanite occurred at temperatures in excess of 840°C, in the presence of a high‐T silicate melt. The Pb concentration gradients preserved in these titanite crystals are used to determine the diffusivity of Pb in titanite under high‐T conditions. We estimate diffusivities ranging from 2 × 10^?22 to 5 × 10^?25 m²/s. These results are significantly lower than experimental data predict yet are consistent with other empirical data on natural titanites, suggesting that Pb diffusivity is similar to that of Sr. Thus our data challenge the wide‐held assumption that U–Pb titanite dates only reflect cooling ages.  相似文献   

Applying VGI to collaborative research in the humanities: the case of ARTL@S     

Catherine Dossin  Nicole Ningning Kong 《制图学和地理信息科学》2017,44(6):521-538

ABSTRACT

Using Artl@s as an example of a project that relies on volunteered geographic information (VGI), this article examines the specific challenges that exist, beyond those frequently discussed in general VGI systems (e.g., participants’ motivation and data quality control) in regard to sharing research data in humanities: (1) most data from the humanities is qualitative and collected from multiple data sources which are often inconsistent and unmappable; (2) data is usually interconnected with multiple relationships among different tables which creates challenges for both mapping and query functionality; (3) data is both geographical and historical. Consequently addresses that no longer exist have to be geolocated and visualized on historical basemaps and spaces must be represented diachronically; (4) the design of web map application needs to balance both sophisticated research requirements and a user-friendly interface; (5) finally contributors expect their data to be cited or acknowledged when used in other studies and users need metadata and citation information in order to reuse and repurpose datasets.

In this article, we discuss how Artl@s, a project which developed a georeferenced historical database of exhibition catalogues, addresses these challenges. Artl@s provides a case study for VGI adoption by digital humanities scholars for research data sharing, as it offers features, such as flexible batch data contribution, interrelated spatial query, automatic geolocalization of historical addresses, and data citation mechanisms.  相似文献   

The Dominican Republic–Central American Free Trade Agreement’s Symbolic Nod to Environmental Protection: Legal Perspectives on the Citizen Submission Process     

J. Christopher Upton  Catherine M. Tucker  Seleste Sanchez 《社会与自然资源》2017,30(10):1277-1287

The Dominican Republic–Central America Free Trade Agreement (CAFTA) contains a chapter on the environment, ostensibly included to mitigate the North American Free Trade Agreement (NAFTA) environmental oversights. The environment chapter created a citizen submission process designed to foster public participation in supporting each participating nation’s environmental laws. This article examines the outcomes to date of the citizen submission process, based on an analysis of the articles of the agreement and an examination of the rulings made on each case submitted under the citizen submission process. The analysis shows that CAFTA poses significant obstacles to citizen participation and has made minimal, if any, contributions to environmental law enforcement among the Parties to the agreement.  相似文献   

Crossing Boundaries in a Collaborative Modeling Workspace     

Jeffrey T. Morisette  Amanda E. Cravens  Brian W. Miller  Marian Talbert  Colin Talbert  Catherine Jarnevich 《社会与自然资源》2017,30(9):1158-1167

There is substantial literature on the importance of bridging across disciplinary and science–management boundaries. One of the ways commonly suggested to cross boundaries is for participants from both sides of the boundary to jointly produce information (i.e., knowledge co-production). But simply providing tools or bringing people together in the same room is not sufficient. Here we present a case study documenting the mechanisms by which managers and scientists collaborated to incorporate climate change projections into Colorado’s State Wildlife Action Plan. A critical component of the project was the use of a collaborative modeling and visualization workspace: the U.S. Geological Survey’s Resource for Advanced Modeling (RAM). Using video analysis and pre/post surveys from this case study, we examine how the RAM facilitated cognitive and social processes that co-produced a more salient and credible end product. This case provides practical suggestions to scientists and practitioners who want to implement actionable science.  相似文献